2 methylbut 2 ene
The hydroboration oxidation of 2-methyl propene yields
Strong oxidizing agents may cause 2-methyl-2-butene to react violently. Exothermic reactions with reducing agents can result in the release of gaseous hydrogen. Exothermic polymerization reactions may occur in the presence of various catalysts (such as acids) or initiators.
Skin and eyes may be irritated or burned as a result of inhalation or contact with the substance. Gases that are annoying, corrosive, and/or poisonous can be created by fire. Dizziness or suffocation may be caused by vapors. Pollution can be caused by runoff from firefighting or dilution water.
Addition reaction of 2-methyl-1,3-butadiene
4-Monoacetals of (E)-2-methylbut-2-ene-1,4-dial of the general formula I ##STR1##, where R1 and R2 are either an aliphatic hydrocarbon radical of 1 to 12 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, or benzyl, or R1 and R2 together form an ethylene or propylene radical which may also be substituted by lower alkyl, are made by a
The present invention is concerned with a method for generating 4-monoacetals of (E)-2-methylbut-2-ene-1,4-dial (2-methylfumardialdehyde) by reacting 2-methylbut-2-ene-1,4-dial or its 1-monoacetal or 1,4-bisacetal with water and/or an alcohol in the presence of an acidic compound. The 4-monoacetals of (E)-2-methylbut-2-ene-1,4-dial are useful building blocks for the synthesis of a variety of biological and pharmacologically active terpenes. Several methods for preparing them have been identified. For eg, acetals and acylals of 3-methylbut-2-enals can be oxidized with selenium dioxide to 4-acetals of (E)-2-methylbut-2-ene-1,4-dial, according to German Laid-Open Applications DOS No. 2,357,752 and DOS No. 2,357,810. Cyclic acetals of 3-methylbut-2-en-4-ol-1-al can be oxidized with sulfuric acid/chromic acid solution to give the corresponding 4-acetals of 2-methylbut-2-ene 1,4-dial, according to the process mentioned in German Laid-Open Application DOS No. 2,225,615.
`2`-methylbut-`2`-ene will be represented as
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How to write the structure for 2-methylbutane
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